WHITE HOUSE, Tenn. — A Kentucky fugitive accused of shooting at police in two states remained on the run, despite a five-day manhunt and a chaotic scene at a small-town Tennessee gas station that ended early today with the arrests of two of his friends.

Floyd Ray Cook, a 62-year-old convicted rapist and robber, has eluded police since Saturday afternoon, when he allegedly shot and wounded a Tennessee police officer.

Two of Cook’s known associates, both with lengthy criminal histories of their own, were arrested after a violent confrontation with U.S. Marshals in White House, Tenn., on Wednesday night, Tennessee Highway Patrol Lt. Bill Miller told reporters.

Marshals, who joined the search for Cook earlier this week, spotted a car they believed to be associated with him at the gas station, just off Interstate 65 north of Nashville, according to the U.S. Marshal Service. An investigator approached the car and the driver attempted to flee, ramming two police cruisers and narrowly missing an officer on foot.

The officer fired a shot at the car. The car careened down a dead-end street, through a fence and into a ravine, Miller said. The two people inside fled on foot into the surrounding cornfields.

Dozens of federal, state and local officers, along with helicopters and K-9 units, descended on rural Robertson County to aid in the hunt.

Police announced they believed Cook was traveling with 50-year-old Troy Wayne, described as an “associate” from Raywick, Ky.

The search team Wednesday night first found Wayne’s girlfriend, 35-year-old Katy McCarty, drenched in water and mud in the field, Miller said. They later found Wayne in a nearby neighborhood. Both were arrested, though police did not specify the charges.

Cook’s whereabouts remained unknown.